Transformation of Oximes and Alcohols to Carbonyl Compounds Using Amberlite IRA-400 Supported Chromic Acid in the Presen

A wide variety of oximes and alcohols were efficiently converted to their corresponding aldehydes and ketones in good to excellent yields using amberlite IRA-400 supported chromic acid in the presence of zirconium tetrachlo-ride in refluxing acetonitrile-H2O. Selective oxidation of oximes and alcohols in the presence of other functional groups such as acetal, hydrazone, aldehyde, ether and alkene can be considered as a noteworthy advantage of this method. A wide variety of oximes and alcohols were efficiently converted to their corresponding aldehydes and ke-tones in good to excellent yields using amberlite IRA-400 supported chromic acid in the presence of zirconium tet-rachloride in refluxing acetonitrile-H2O. Selective oxidation of oximes and alcohols in the presence of other func-tional groups such as acetal, hydrazone, aldehyde, ether and alkene can be considered as a noteworthy advantage of this method.

作 者： BAHRAMI, Kiumars KHODAEIMohammad-Mehdi GORGIN-KARAJI, Usef   作者單位： Department of Chemistry,Razi University,Kermanshah 67149,Iran Nanoscience and Nanotechnology Research Center (NNRC),Razi University,Kermanshah 67149,Iran  刊 名： 中國(guó)化學(xué)（英文版）  SCI 英文刊名： CHINESE JOURNAL OF CHEMISTRY  年，卷(期)： 2009 27(2)  分類號(hào)： O6  關(guān)鍵詞： oxidation   amberlite IRA-400   oxime   alcohol  

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